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Creators/Authors contains: "Tansky, Maxym"

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  1. ; ; ; ; ; ; (, Dalton Transactions)
    We report discrete divanadium complexes of 1,8-naphthyridine-2,7-dicarboxylate, characterized by SCXRD, DFT modelling, and magnetometry. One complex shows significantly greater activity in the aerobic cleavage of diols and a lignin model compound than its monometallic analogs. Mechanistic experiments and a substrate-bound complex provide insight into cooperativity in vanadium redox catalysis. 
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    Free, publicly-accessible full text available October 21, 2026